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Selective Functionalization of Hydrocarbons by Nitric Acid and Aerobic Oxidation Catalyzed by N-Hydroxyphthalimide and Iodine under Mild Conditions.

✍ Scribed by Francesco Minisci; Francesco Recupero; Cristian Gambarotti; Carlo Punta; Roberto Paganelli


Publisher
John Wiley and Sons
Year
2003
Weight
150 KB
Volume
34
Category
Article
ISSN
0931-7597

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Hydroperoxidation of Tertiary Alkylaroma
✍ Lucio Melone; Cristian Gambarotti; Simona Prosperini; Nadia Pastori; Francesco R πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 350 KB πŸ‘ 1 views

## Abstract A metal‐free catalytic system consisting of an aldehyde and __N__‐hydroxyphthalimide (NHPI) for the selective oxidation of tertiary alkylaromatics with molecular oxygen has been developed. Cumene was oxidized efficiently to the corresponding hydroperoxide under mild conditions. The mole