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A new selective free radical synthesis of aromatic aldehydes by aerobic oxidation of tertiary benzylamines catalysed by N-hydroxyimides and Co(II) under mild conditions. Polar and enthalpic effects

✍ Scribed by Andrea Cecchetto; Francesco Minisci; Francesco Recupero; Francesca Fontana; Gian Franco Pedulli

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 107 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00474-4

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✦ Synopsis

Tertiary benzylamides are easily and selectively converted into aldehydes by molecular oxygen; the reaction is catalysed by N-hydroxyamides and Co(II).

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