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Recent Developments in the Osmium-Catalyzed Dihydroxylation of Olefins

✍ Scribed by Uta Sundermeier; Christian Doebler; Matthias Beller

Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Osmium-Catalyzed Dihydroxylation of Olef
Osmium-Catalyzed Dihydroxylation of Olefins in Acidic Media: Old Process, New Tricks
✍ Philippe Dupau; Robert Epple; Allenβ€…A. Thomas; Valeryβ€…V. Fokin; K.β€…Barry Sharple πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 179 KB πŸ‘ 2 views

A screen of over 500 diversely functionalized additives in osmium-catalyzed dihydroxylation has uncovered that electron-deficient olefins are converted into the corresponding diols much more efficiently when the pH of the reaction medium is maintained on the acidic side. Further studies have identif