Osmium-Catalyzed Dihydroxylation of Olef
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Philippe Dupau; Robert Epple; Allen A. Thomas; Valery V. Fokin; K. Barry Sharple
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Article
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2002
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John Wiley and Sons
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English
⚖ 179 KB
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A screen of over 500 diversely functionalized additives in osmium-catalyzed dihydroxylation has uncovered that electron-deficient olefins are converted into the corresponding diols much more efficiently when the pH of the reaction medium is maintained on the acidic side. Further studies have identif