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Rearrangements of β,γ-epoxysilanes to β-sillyl aldehydes and ketones

✍ Scribed by Paul F. Hudrlik; Gregory P. Withers


Book ID
104212904
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
257 KB
Volume
17
Category
Article
ISSN
0040-4039

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On the acid-catalyzed rearrangement of β
✍ Harold Hart; George M. Love 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 160 KB

The rearrangement of R,y-unsaturated ketones in acid has considerable potential for the synthesis of unusual bi-and tricyclic ring systems. In most examples described thus far, however, the double bond is present in the relatively strained cyclobutene ring.' We describe here a synthetically useful r