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Unexpected Oxadi-π-methane Rearrangement of β,γ-Unsaturated Aldehydes

✍ Scribed by Armesto, Diego; Ortiz, Maria J.; Romano, Santiago; Agarrabeitia, Antonia R.; Gallego, Mar G.; Ramos, Ana

Book ID
126198195
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
290 KB
Volume
61
Category
Article
ISSN
0022-3263

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Alihough preview stu&s have shown that acyclic j3.r\_unsaturated oximea and oxime ethers do not undergo the aza-dl-mmethane {ADPM) rmrrangewmt. the Z-nu~l~,4dipAm~-2-~nylb~-3-~1 oxiww Sm. its wwhyl ether 51 and the 2,2.4,4-tetraphenylbnt-3-enal oxime I4 give the correapondhg cydopropyl derbatives &,