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The aza-di-π-methane rearrangement of β-γ-unsaturated oximes

✍ Scribed by Diego Armesto; Ana Ramos; Elena P. Mayoral

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
343 KB
Volume
35
Category
Article
ISSN
0040-4039

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✦ Synopsis

Alihough preview stu&s have shown that acyclic j3.r_unsaturated oximea and oxime ethers do not undergo the aza-dl-mmethane {ADPM) rmrrangewmt. the Z-nu~l~,4dipAm~-2-~nylb~-3-~1 oxiww Sm. its wwhyl ether 51 and the 2,2.4,4-tetraphenylbnt-3-enal oxime I4 give the correapondhg cydopropyl derbatives &,8b and IS by the ADPM path, tn a remtion that Is controfled by the stab&y Opthe tntennediate f3-bira&al.

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