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Rearrangements in 1,3-dipolar additions to 3,3-dimethylcycloproprene. The effect of ring strain on the rate of 1,3-dipoLar addition.

✍ Scribed by Donald H. Aue; Gregory S. Helwig

Book ID
104234644
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
244 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

We have found that 1,3-dipolar additions to 3,3-dimethylcyclopropene sometimes give rearranged products, but the rearrangement products all derive from a normal 1,3-dipolar adduct.

Wo products from 3,3-dimethylcyclopropene or methylenecyclopropane' additions have been found that would correspond to a cyclopropyl to ally1 rearrangement of an intermediate in a stepwise addition.

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