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The first 1,3-dipolar addition to a benzothiophene s-oxide

โœ Scribed by P. Geneste; R. Durand; D. Pioch

Book ID
104238063
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
129 KB
Volume
20
Category
Article
ISSN
0040-4039

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Rearrangements in 1,3-dipolar additions
Rearrangements in 1,3-dipolar additions to 3,3-dimethylcycloproprene. The effect of ring strain on the rate of 1,3-dipoLar addition.
โœ Donald H. Aue; Gregory S. Helwig ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 244 KB

We have found that 1,3-dipolar additions to 3,3-dimethylcyclopropene sometimes give rearranged products, but the rearrangement products all derive from a normal 1,3-dipolar adduct. Wo products from 3,3-dimethylcyclopropene or methylenecyclopropane' additions have been found that would correspond to