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Rearrangement of linalool, geraniol, nerol and their derivatives

✍ Scribed by Cori, Osvaldo; Chayet, Liliana; Perez, Luz Maria; Bunton, Clifford A.; Hachey, David

Book ID: 121362482
Publisher: American Chemical Society
Year: 1986
Tongue: English
Weight: 928 KB
Volume: 51
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00358a028

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## Introduction. Z-E conformational isomerism of the title compounds has been a long-standing problem in terpene chemistry. In most literature the Z-("cis")-conformation is assigned to nerol, the E-("trans")-conformation to geraniol. In 1965, Rummens 1) reversed these assignments, based mainly on