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Rearrangement of 10-ethyl-2-keto-Δ1(9);3(4)-hexahtdronaphthalene

✍ Scribed by K.H. Bell


Book ID
104224095
Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
153 KB
Volume
8
Category
Article
ISSN
0040-4039

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Photochemical rearrangements of 2-carbox
✍ Drury Caine; John F. DeBardeleben Jr; J. Byron Dawson 📂 Article 📅 1966 🏛 Elsevier Science 🌐 French ⚖ 291 KB

Recently, we reported the conversion of 2-fonqyl-3-keto-9-methyl-Al,4 -hexahydronaphthalene into a perhydroazulene derivative by irradiation in aqueous acetic acid followed by base treatment of the photo-product (1). We now have found that L4 2-carboxy-3-keto-g-methyl-A -hexahydronaphthalene (I) is