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Notes- Stereochemistry of 8,10-Di-methyl-2-keto-Δ 1,9,3,4 -hexahydronaphthalene

✍ Scribed by Bloom, Stanley


Book ID
126253525
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
432 KB
Volume
24
Category
Article
ISSN
0022-3263

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The conversion of 2-formyl-3-keto-9-meth
✍ Drury Caine; John F. DeBardeleben Jr.; School of Chemistry 📂 Article 📅 1965 🏛 Elsevier Science 🌐 French ⚖ 247 KB

We have found that on irradiation in aqueous acetic acid followed by base catalyzed defomylatlon of the c-de photo-product, the 2-fonqyl dienone III is converted into the5/7-fused dienone IV in 7% overall yield. Ccmpound III was prepared from the octalone I (1) by a procedure similar to that employ