Rate constants for the recombination reaction OD + NO, + M-DNO, + M have been determined in the falloff region (5-500 torr) and a t 297 -C 2 K, in the presence of He, N,, and SF, as third bodies, by using a pulsed laser photolysis-resonance absorption technique. Values of KO, k x and the falloff par
Real-time kinetic study of the reaction F+NO2
β Scribed by Fasano, D. M.
- Book ID
- 121506446
- Publisher
- American Institute of Physics
- Year
- 1983
- Tongue
- English
- Weight
- 627 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0021-9606
- DOI
- 10.1063/1.444668
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π SIMILAR VOLUMES
A pulse radiolysis system was used to study the kinetics of the reaction of CF&FH02 with NOz. By monitoring the rate of the decay of NO\* using its absorption at 400 nm the reaction rate constant was determined to be k= (5.OkO.S) x 10-r' cm3 molecule-' s-'. A long path length Fourier-transform infra
Ground state atomic sulfur was generated by 193-nm laser photolysis of CS 2 precursor in Ar bath gas, in the presence of a large excess of NO 2 under pseudo-first-order conditions. Decays of S( 3 P J ) were monitored over 292-656 K and pressures of 14-535 mbar. No pressure dependence was observed, a
The third order r a t e coefficients for t h e addition reaction of C1. with NOz, C1 + NOz + M-, CINOz (ClONO) + M; K,, were measured to be k,(He) = (7.5 t 1.1) x cm6 molecule-2s-1 a t 298 K using the flash photolysis-resonance fluorescence method. The pressure range of the study was 15 to 500 torr