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A kinetics study of the reaction of Cl with NO2

✍ Scribed by A. R. Ravishankara; G. J. Smith; D. D. Davis

Publisher: John Wiley and Sons
Year: 1988
Tongue: English
Weight: 229 KB
Volume: 20
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550201005

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✦ Synopsis

The third order r a t e coefficients for t h e addition reaction of C1. with NOz, C1 + NOz + M-, CINOz (ClONO) + M; K,, were measured to be k,(He) = (7.5 t 1.1) x cm6 molecule-2s-1 a t 298 K using the flash photolysis-resonance fluorescence method. The pressure range of the study was 15 to 500 torr He and 19 to 200 torr Nz. The temperature dependence of the third order rate coefficients were also measured between 240 and 350 K. The 298 K results are compared with those from previous low pressure studies. cm6 molecule-zs-l and kl(N2) = (16.6 * 3.0) x

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