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Kinetic study of the recombination reaction OD + NO2 + M → DNO3 + M

✍ Scribed by Alain R. Bossard; Donald L. Singleton; George Paraskevopoulos

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
606 KB
Volume
20
Category
Article
ISSN
0538-8066

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✦ Synopsis

Rate constants for the recombination reaction OD + NO, + M-DNO, + M have been determined in the falloff region (5-500 torr) and a t 297 -C 2 K, in the presence of He, N,, and SF, as third bodies, by using a pulsed laser photolysis-resonance absorption technique. Values of KO, k x and the falloff parameter F, have been estimated. Our rate constants were, within the experimental uncertainty, the same as those reported for the reaction of OH radicals with NO,.

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