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Reagent Influence on the Direction of Nucleophilic Substitution in 1,4-Nitrochloroanthraquinone

✍ Scribed by Albina A. Tabatskaya; Elena F. Kutasheva; Vladislav M. Vlasov

Book ID: 111729506
Publisher: Royal Society of Chemistry
Year: 1993
Tongue: English
Weight: 335 KB
Volume: 3
Category: Article
ISSN: 0959-9436
DOI: 10.1070/mc1993v003n04abeh000270

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## Abstract Reactions of carbanions of aryl chloromethyl and dichloromethyl sulfones 3 and 4 and __tert__‐butyl chloro‐ and dichloroacetates (5 and 6) with 1‐halo‐2,4‐dinitrobenzenes 1 and 2 proceed by nucleophilic replacement of a hydrogen atom. The S~N~Ar of the halogen atom occurs to a negligibl