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Changes of selectivity in the reactions of substituted 4-nitrobenzyl sulfonates with nucleophilic reagents

โœ Scribed by Dietze, Paul; Jencks, William P.


Book ID
127119847
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
951 KB
Volume
111
Category
Article
ISSN
0002-7863

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The nucleophilic addition of organic anions to aromatic compounds with halogens positioned both ortho and para to activating groups was studied in a variety of solvents. Substrates showed strong preferences for ortho substitution in most cases. Evidence is presented for activating group-dependent co