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Novel substitution reactions of 5-(4-nitrophenyl)-10, 15, 20-triphenyl-porphyrin with nucleophilic reagents

✍ Scribed by Shao Zhi-jun; Ou Yang-yan; Hu Qin; Zeng Dan-li; Chen Zhang-ping

Book ID
105626399
Publisher
Wuhan University
Year
2005
Tongue
English
Weight
490 KB
Volume
10
Category
Article
ISSN
1007-1202

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✍ Tapan Kumar Saha; Subarna Karmaker; Keietsu Tamagake πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 279 KB πŸ‘ 3 views

High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o