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Reactivity of heterocyclic compounds. VI. 2,6-Diaminopyrimidine-5-carbonitriles and 3,5-Dicyanopyridones from 2-amino-4H-pyran-3, 5-dicarbonitriles

โœ Scribed by Dr. C. Seoane; Dr. J. L. Soto; M. Quinteiro


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
460 KB
Volume
328
Category
Article
ISSN
1615-4150

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๐Ÿ“œ SIMILAR VOLUMES


Synthesis of heterocyclic compounds VII.
โœ M. Quinteiro; C. Seoane; J.L. Soto ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 121 KB

Only few methods for 4H-pyran synthesis are known. In them, carbonyl compounds (Z-4). pyrylium salts (5-7) or y-pyrones (8.9) a're used as starting materials.

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Synthesis of Substituted 2-Amino-5-nitro-4H-pyran-3-carbonitriles. -The reaction of ฮฑ-nitroketone (I) with benzylidenemalononitriles (II) catalyzed by Et 3 N represents the first example of a synthesis of nitropyrans (III) from ฮฑ-nitroketones.