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Reactivity of .beta.-Amino Alcohols with Carbon Disulfide Study on the Synthesis of 2-Oxazolidinethiones and 2-Thiazolidinethiones

โœ Scribed by Delaunay, Dominique; Toupet, Loiec; Corre, Maurice Le


Book ID
120014013
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
471 KB
Volume
60
Category
Article
ISSN
0022-3263

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Synthesis of chiral oxazolidin-2-ones by
โœ Marta Feroci; Armando Gennaro; Achille Inesi; Monica Orsini; Laura Palombi ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 316 KB

An improved electrochemical synthesis of chiral oxazolidin-2-ones from chiral 1,2-amino alcohols is obtained by direct electrolysis of solutions of MeCN-TEAP containing the amino alcohol, with subsequent CO 2 bubbling and addition of TsCl. This synthesis avoids any addition of bases or probases and