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Synthesis of chiral oxazolidin-2-ones by 1,2-amino alcohols, carbon dioxide and electrogenerated acetonitrile anion

✍ Scribed by Marta Feroci; Armando Gennaro; Achille Inesi; Monica Orsini; Laura Palombi

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 316 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)01186-3

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✦ Synopsis

An improved electrochemical synthesis of chiral oxazolidin-2-ones from chiral 1,2-amino alcohols is obtained by direct electrolysis of solutions of MeCN-TEAP containing the amino alcohol, with subsequent CO 2 bubbling and addition of TsCl. This synthesis avoids any addition of bases or probases and yields oxazolidinones in high yields.

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