The Reaction of 1,2-Amino Alcohols with Carbon Dioxide in the Presence of 2-Pyrrolidone Electrogenerated Base. New Synthesis of Chiral Oxazolidin-2-ones
β Scribed by Casadei, M. Antonietta; Feroci, Marta; Inesi, Achille; Rossi, Leucio; Sotgiu, Giovanni
- Book ID
- 127294028
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 63 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
An improved electrochemical synthesis of chiral oxazolidin-2-ones from chiral 1,2-amino alcohols is obtained by direct electrolysis of solutions of MeCN-TEAP containing the amino alcohol, with subsequent CO 2 bubbling and addition of TsCl. This synthesis avoids any addition of bases or probases and
As a part of our continuing studies on the organic selenium chemistry, we reported that ureas can be synthesized by the reaction of carbon monoxide with ammonia or amines in the presence of selenium catalyst and oxygen. 1,2) The formation of ureas in such cases was interpreted as involving the react
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