✦ LIBER ✦

Reactivity of Ammonium Chloride/Mercuric Chloride Mixtures with Monel Containers. The New Compounds (NH4)2(NH3)x[Ni(NH3)2Cl4] and (NH4)5Cl2[CuCl2][CuCl4]

✍ Scribed by Gerd Meyer; Peter Nockemann

Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 376 KB
Volume: 162
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.2001.9282

No coin nor oath required. For personal study only.

✦ Synopsis

Ammonium chloride/mercuric chloride mixtures (molar ratio 2:1) react at 3503 3C with Monel (Cu68Ni32) to yield (NH 4 )NiCl 3 and mercury and copper amalgam, respectively. With larger amounts of (NH 4 )Cl in the reaction mixture, dark green

is also formed as a main product. Light blue crystals of the mixed-valent copper(I,II) chloride (NH 4 ) 5 Cl 2 [CuCl 2 ][CuCl 4 ] (2) were obtained as a minor byproduct from a 4:1 reaction mixture. The crystal structures were determined from single crystal X-ray data; (1): tetragonal, I4/mmm, a ‫؍‬ 770.9(1), c ‫؍‬ 794.2(2) pm, 190 re6ections, R 1 ‫؍‬ 0.0263; (2): tetragonal, I4/mcm, a ‫؍‬ 874.8(1), c ‫؍‬ 2329.2(3) pm, 451 re6ections, R 1 ‫؍‬ 0.0736. In (1) Ni 2؉ resides in trans-[Ni(NH 3 ) 2 Cl 4 ] 2؊ octahedra, and in (2) copper(I) is linearly two-coordinated in [CuCl 2 ] ؊ and copper(II) resides in a 6attened tetrahedron [CuCl 4 ] 2؊ with a tetrahedricity of 89%.

📜 SIMILAR VOLUMES

ChemInform Abstract: Action of Ammonium

ChemInform Abstract: Action of Ammonium Chloride and Bromide on Vanadium, Niobium and Tantalum: Synthesis and Crystal Structures of (NH4)2(V(NH3)X5), (NH4)6( (M5(NH)4)X17) (M: Nb, Ta), (NH4)2(NbX6), and (NH4)3(Ta2NX10) (X: Cl, Br).

✍ M. SIMON; G. MEYER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Action of Ammonium Chloride and Bromide on Vanadium, Niobium and Tantalum: Synthesis and Crystal Structures of (NH4)2(V(NH3)X5), (NH4)6( (M5(NH)4)X17) (M: Nb, Ta), (NH4)2(NbX6), and (NH4)3(Ta2NX10) (X: Cl, Br). -The reaction of NH4Cl or NH4Br with metallic V, Nb, and Ta at moderate temp. (320-430 •

Synthesis and Structure of a New Compoun

Synthesis and Structure of a New Compound (NH4)3 [{Ta2(NH)3Cl6}Cl], with a Novel Imido-Bridged Chain: 1∞ [Ta2(NH)3Cl6]2-.

✍ P. Subramanya Herle; Joachim Straehle 📂 Article 📅 2003 🏛 John Wiley and Sons ⚖ 61 KB 👁 1 views

ChemInform Abstract: Structural Studies

ChemInform Abstract: Structural Studies of New Sulfito Mercurates(II) with General Formula xM[XHgSO3] ×yHgX2×zMX×nH2O (M: NH4, K; X: Cl, Br).

✍ Matthias Weil; Stefan Baumann; Dietrich K. Breitinger 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 17 KB

Syntheses of K[Co(tren)(NH3)(SO4)](S4O6)

Syntheses of K[Co(tren)(NH3)(SO4)](S4O6)·2(H2O) and of [cis-α-Co(trien)(NH3)Cl](S5O6) – Compounds Produced by Hydrolytic Cleavage of Sulfur–Sulfur Bonds of the Tetrathionate Anion

✍ Hyungphil Chun; Ivan Bernal 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 345 KB 👁 1 views

Syntheses of K

On Oxohalogen Niobates(V) M2[Nb3O5X7] (M

On Oxohalogen Niobates(V) M2[Nb3O5X7] (M: NH4, K, Rb, Cs; X: Cl, Br) — New Members of a Compound Family with a Layered Structure.

✍ Johannes Beck; Jairo Bordinhao; Christian Kusterer 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 15 KB 👁 1 views