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Synthesis and Structure of a New Compound (NH4)3 [{Ta2(NH)3Cl6}Cl], with a Novel Imido-Bridged Chain: 1∞ [Ta2(NH)3Cl6]2-.

✍ Scribed by P. Subramanya Herle; Joachim Straehle


Publisher
John Wiley and Sons
Year
2003
Weight
61 KB
Volume
34
Category
Article
ISSN
0931-7597

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Action of Ammonium Chloride and Bromide on Vanadium, Niobium and Tantalum: Synthesis and Crystal Structures of (NH4)2(V(NH3)X5), (NH4)6( (M5(NH)4)X17) (M: Nb, Ta), (NH4)2(NbX6), and (NH4)3(Ta2NX10) (X: Cl, Br). -The reaction of NH4Cl or NH4Br with metallic V, Nb, and Ta at moderate temp. (320-430 •