𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactivity of 1-alkoxy π-allylpalladium complexes

✍ Scribed by Nicolas Vicart; Bernard Cazes; Jacques Goré

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
209 KB
Volume
36
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of 1β-Methylcarbapenem Antibio
Synthesis of 1β-Methylcarbapenem Antibiotic Precursors by Cyclization Using π-Allylpalladium Complexes
✍ Jean-Christophe Galland; Sylvain Roland; Joël Malpart; Monique Savignac; Jean-Pi 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 302 KB

An efficient diastereoselective multi-step synthesis of in the hydrogenation step to control the β-stereochemistry at the 1-position, and a π-allylpalladium ring-closure strategy is bicyclic 1β-methylcarbapenem antibiotic precursors has been developed, starting from the commercially available 4-used

Kinetics and Mechanisms of the Reactions
Kinetics and Mechanisms of the Reactions of π-Allylpalladium Complexes with Nucleophiles
✍ Oliver Kuhn; Herbert Mayr 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 133 KB 👁 1 views

Which nucleophiles are capable of attacking the allyl ligand of the Pd-stabilized allyl cation 1? This question is answered by the electrophilicity parameter of 1 which is derived from kinetic investigations.