𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics and Mechanisms of the Reactions of π-Allylpalladium Complexes with Nucleophiles

✍ Scribed by Oliver Kuhn; Herbert Mayr


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
133 KB
Volume
38
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

✦ Synopsis


Which nucleophiles are capable of attacking the allyl ligand of the Pd-stabilized allyl cation 1? This question is answered by the electrophilicity parameter of 1 which is derived from kinetic investigations.


📜 SIMILAR VOLUMES


Three-component coupling polymerization
✍ Nobuyuki Miyaki; Ikuyoshi Tomita; Takeshi Endo 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB

A novel palladium-catalyzed three-component polycondensation of 1,2,10,11dodecatetraene, 4,4 -diiodobiphenyl, and nucleophiles was carried out using various carbanions and amines as a nucleophilic part. The polymerization with various sodium diethyl malonates produced polymers in high yields. Partic

Kinetics and mechanism of reaction of to
✍ S. B. Jonnalagadda; N. Musengiwa 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 1 views

The detailed kinetics of the reaction of toluidine blue {phenothiazine-5-ium, 3amino-7(dimethylamino)-2-methyl chloride, tolonium chloride, with potassium bro-ϩ Ϫ TB Cl } mate and with aqueous bromine reaction were studied. In most of the experiments, the kinetics were monitored by following the rat

Kinetics and mechanisms of the reactions
✍ G. S. Tyndall; J. J. Orlando; T. J. Wallington; M. Dill; E. W. Kaiser 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 201 KB 👁 1 views

chlorine chemistry and hydrocarbon chemistry has taken on new importance in the last few years with the realization that chlorine chemistry may play a more important role in the marine troposphere than previously thought. Measurements of hydrocarbons in the Arctic troposphere in springtime have prov