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Reactivity and π-facial selectivity of nucleophile addition to the radical cations of 7-benzhydrylidenenorbornene derivatives

✍ Scribed by Hideki Ishii; Satoshi Shiina; Takashi Hirano; Haruki Niwa; Mamoru Ohashi

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
258 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

For correlating a homoconjugation structure of a radical cation to its reactivity with a nucleophile, the reactivity and rr-facial selectivity of CH3OH and H20 addition to the radical cations of 7-benzhydrylidenenorbornene derivatives generated by photoinduced electron transfer reactions were investigated.

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