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ChemInform Abstract: Reactivity and π-Facial Selectivity of Nucleophile Addition to the Radical Cations of 7-Benzhydrylidenenorbornene Derivatives.

✍ Scribed by Hideki Ishii; Satoshi Shiina; Takashi Hirano; Haruki Niwa; Mamoru Ohashi

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reactivity and π-Facial Selectivity of Nucleophile Addition to the Radical Cations of 7-Benzhydrylidenenorbornene Derivatives.

-For correlating a homoconjugation structure of a radical cation to its reactivity with a nucleophile, the reactivity and π-facial selectivity of MeOH and H 2 O addition to the radical cations of norbornene derivatives, generated by photoinduced electron-transfer reactions, is investigated. -(ISHII, HIDEKI;

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