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Reactions of Tris-(2,2′-bipyrimidine)iron(II) with cyanide and azide ions in aqueous solution

✍ Scribed by Robert J. Wademan; Peter A. Williams


Publisher
Springer
Year
1979
Tongue
English
Weight
161 KB
Volume
4
Category
Article
ISSN
0340-4285

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Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F

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