The electrode processes of tris(2,2'-bipyridine)iron(II) and tris(2,2'-bipyridine)iron(III) complexes at the rotated platinum electrode and the dropping mercury electrode (dme) in acetonitrile solutions have been investigated by the measurement of current/potential curves, dc and ac polarograms and
Reactions of Tris-(2,2′-bipyrimidine)iron(II) with cyanide and azide ions in aqueous solution
✍ Scribed by Robert J. Wademan; Peter A. Williams
- Publisher
- Springer
- Year
- 1979
- Tongue
- English
- Weight
- 161 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0340-4285
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Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F
The kinetics of dissociation of tris-2,2'-bipyridyl-iron(II) complex ion have been examined in aqueous acetic acid solutions. The reaction is first order in the complex ion; the dependence of rate on H' is somewhat like that observed in aqueous solutions approaching a limiting value at higher H' con