The kinetics of dissociation of tris-2,2'-bipyridyl-iron(II) complex ion have been examined in aqueous acetic acid solutions. The reaction is first order in the complex ion; the dependence of rate on H' is somewhat like that observed in aqueous solutions approaching a limiting value at higher H' con
Kinetics and mechanisms of dissociation of tris(2,2′-bipyridine)iron(II) complex in aqueous salts solutions
✍ Scribed by Matthieu Tubino; Eduardo J.S. Vichi
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 571 KB
- Volume
- 131
- Category
- Article
- ISSN
- 0020-1693
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Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F