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Reactions of trimethylsilyl azide with aldehydes: facile and convenient syntheses of diazides, tetrazoles, and nitriles

✍ Scribed by Kozaburo Nishiyama; Makoto Oba; Akio Watanabe

Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 774 KB
Volume: 43
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)90003-1

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✦ Synopsis

The reactfons of trimethylsilyl azide ITMSA) with various afdehydes were found to be versatile procedures for the synthesis of gem-and 1,3-dfazides, tetrazoles, and nitriles, whoae formation ~88 varied by controlling the quantities of TNSA, catalyst, and the reaction conditions.

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