✦ LIBER ✦
Reactions of cuprous methyltrialkylborates obtainable from trialkylboranes with acrylonitrile, ethyl acrylate and 1-acyl-2-vinylcyclopropane. Convenient syntheses of nitriles, carboxylic esters and γ,δ-unsaturated ketones
✍ Scribed by Norio Miyaura; Mitsuomi Itoh; Akira Suzuki
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- French
- Weight
- 212 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Dreviously, we have reported that organoboranes undergo a spontaneous 1,4-adcl~tlon reactlon in the presence of oxygen to numerous ketone,1 u,a-unsaturated carbonyl compounds Including methyl vinyl acetylacetylene, 2 1,3-butadlene monoxlde,3 3,4-epoxy-?-butyne,4 and crotonal&m7ne, 5