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Reactions of the Tetrahedral Clusters [MCo 3 (CO) 12 ] - (M = Ru, Fe) with Functional Mono- and Diynes

✍ Scribed by Choualeb, Aldjia; Braunstein, Pierre; Rosé, Jacky; Welter, Richard


Book ID
127137656
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
435 KB
Volume
43
Category
Article
ISSN
0020-1669

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59Co and 99Ru NMR investigation of heter
✍ Pierre Braunstein; Jacky Rosé; Pierre Granger; Thierry Richert 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 467 KB

## Abstract A series of mixed‐metal carbonyl clusters containing Co and Ru atoms was investigated by ^59^Co NMR and, for the first time in cluster chemistry, by ^99^Ru NMR. These techniques were successfully used to follow the reactivity of these complexes towards nitrosylation by NO^+^. Whereas [N