Vibrational spectroscopic investigation of metal cluster prototypes in the solid state: [M3(CO)12], where M = Os, Ru; metal-ligand stretching and MCO deformation region

Vibrational spectroscopic investigation

Vibrational spectroscopic investigation of metal cluster prototypes in the solid state: A novel approach to the CO stretching region in [Os3(CO)12] and [Ru3(CO)12]

✍ Christopher E. Anson; Upali A. Jayasooriya 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 645 KB

A detailed assignment of the v(C0) region of [Os,(CO),,] and [Ru~(CO),~] in the solid state is obtained by using relative intensities of these vibrational modes in the i.r. and Raman spectra. A qualitative intensity prediction is possible by recognizing that the real crystal structure of these solid