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Substitution reactions of the trimeric dodecacarbonylsM3(CO)12(M=Fe, Ru, or Os) and their derivativesM3(CO)12−nLn(n=1–3)

✍ Scribed by Brian F. G. Johnson; Yvonne V. Roberts


Book ID
104896073
Publisher
Springer
Year
1993
Tongue
English
Weight
840 KB
Volume
4
Category
Article
ISSN
1040-7278

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The Photochemistry of M3(CO)12 (M = Ru,
✍ Nicholas E. Leadbeater; Jack Lewis; Paul R. Raithby; Gregory P. Ward 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 167 KB

The photochemistry of M 3 (CO) 12 [M = Ru (1a), Os (1b)] with HOs 3 (CO) 10 (C 3 H 3 N 2 ) (2b). Photolysis of 1a and 1b with 3,5dimethylpyrazole yields HRu 3 (CO) 10 (C 3 HMe 2 N 2 ) (4a) and pyrazole, 3,5-dimethylpyrazole, and 3,5-diphenylpyrazole is documented. With 1a, photolysis with pyrazole l