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Phosphine-substituted and phosphido-bridged metal clusters in homogeneous catalysis: I. Synthesis and reactivity of (η5-C5H5)NiM3(μ-H)3(CO)9−nLn (M  Ru, Os, n  1,2: L  PPh3, PPh2H, PCy3, PEt3) and M3(CO)12−nLn (M  Ru; n  1-3: L  PPh3, PPh2H, PCy3, PEt3; M  Os, n  1,2; L  PPh3)

✍ Scribed by Mario Castiglioni; Roberto Giordano; Enrico Sappa

Book ID
107811061
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
855 KB
Volume
342
Category
Article
ISSN
0022-328X

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Phosphine-substituted and phosphido-brid
Phosphine-substituted and phosphido-bridged clusters in homogeneous catalysis: III. Selective hydrogenation of t-butylacetylene in the presence of Ru3(CO)12-n(PPh2H)n (n = 2, 3), HRu3(CO)10-(μ-PPh2), HRu3(CO)9(μ-PPh2), H2Ru3(CO)8(μ-PPh2)2 and HRu3(CO)7(μ-PPh2)3. Spectroscopic identification of common alkyne-substituted cluster intermediates
✍ Mario Castiglioni; Roberto Giordano; Enrico Sappa 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 794 KB