Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2
Reactions of the Perfluoroalkyltriazapentadiene Ph 2 N 3 C 2 (C 3 F 7 ) 2 H with Acids, Bases, and Water
β Scribed by Siedle, A. R.; Webb, Robert J.; Brostrom, Myles; Chou, Shih-Hung; Weil, David A.; Newmark, Richard A.; Behr, Fred E.; Young, Victor G.
- Book ID
- 121475878
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 126 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
The reactions between F2 and the lowest members of the homologous series of perfluoroalkyl iodides (CF31. C2F51. and n-C3F71) have been studied. For these compounds, an exponential decrease in the alkyl iodide concentration over time following an induction period is observed for certain experimental
The reactions of some perfluoroalkyl radicals with carbon tetrachloride have been studied using the photolysis of the corresponding perfluoroalkyl iodide as the free radical source. The Arrhenius parameters, based on the value of 2.3 x 1013 cm3 mol-' s-' for the self-combination rate constant of all