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Reactions of the HO 2 Radical with CH 3 CHO and CH 3 C(O)O 2 in the Gas Phase

โœ Scribed by Tomas, Alexandre; Villenave, Eric; Lesclaux, Robert

Book ID
127119170
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
123 KB
Volume
105
Category
Article
ISSN
1089-5639

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The gas phase reaction of the hydroxyl radical with the unsaturated peroxyacyl nitrate has been studied at 298 2 2 K and atmospheric pressure. The OH-MPAN reaction rate constant relative to that of OH + n-butyl nitrate is 2.08 2 0.25. This ratio, together with a literature rate constant of 1.74 X c