A Systematic Computational Study on the Reactions of HO 2 with RO 2 : The HO 2 + CH 3 O 2 (CD 3 O 2 ) and HO 2 + CH 2 FO 2 Reactions
β Scribed by Hou, Hua; Wang, Baoshan
- Book ID
- 126034952
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 324 KB
- Volume
- 109
- Category
- Article
- ISSN
- 1089-5639
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Fourier transform infrared spectroscopy was used to identify CHrOCHO and CH,OCH,OOH as products of the gas-phase reaction of CH,0CH202 radicals with HO1 radicals. At 700 Torr and 2952 2 K, branching ratios of k,./k, =0.53 f 0.08 and klb/ k, =0.40\* 0.04 were established. Quoted errors are 2 standard
The kinetics of the self-reactions of HO 2 , CF 3 CFHO 2 , and CF 3 O 2 radicals and the cross reactions of HO 2 with FO 2 , HO 2 with CF 3 CFHO 2 , and HO 2 with CF 3 O 2 radicals, were studied by pulse radiolysis combined with time resolved UV absorption spectroscopy at 295 K. The rate constants f