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Reactions of the HCN-Tetramer with Aldehydes

✍ Scribed by Klemens Koch; W. Bernd Schweizer; Albert Eschenmoser

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
218 KB
Volume
4
Category
Article
ISSN
1612-1872

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## Abstract Photochemical reactions of caffeine with several aliphatic aldehydes are performed. In the reactions with ethanal, propanal and butanal stable 8‐acyl‐8,9‐dihydrocaffeines 2 and 3 together with unreduced 8‐acylcaffeines 4 and 8‐(α‐hydroxyalkyl)caffeines 6 are produced. Under similar cond

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