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Reactions of Silicon Atoms with Nitrogen: A Combined Matrix Spectroscopic and Density Functional Theory Study 1

✍ Scribed by Maier, Günther; Reisenauer, Hans Peter; Glatthaar, Jörg

Book ID
121438966
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
124 KB
Volume
19
Category
Article
ISSN
0276-7333

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Dimethoxydimethylsilane from Silicon Ato
Dimethoxydimethylsilane from Silicon Atoms and Dimethyl Ether: A Combined Matrix-Spectroscopic and Density Functional Theory Study
✍ Günther Maier; Jörg Glatthaar 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 250 KB

## Abstract The reaction between silicon atoms and dimethyl ether (**6**) has been studied in an argon matrix at 10 K and in solid dimethyl ether (**6**) at temperatures up to 80 K. In the initial step, a triplet n‐adduct **T‐5** is formed between a silicon atom and **6**. The next step needs photo