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Bromocyanocarbene and Bromoisocyanocarbene: A Combined Matrix-Spectroscopic and Density Functional Theory Study

✍ Scribed by Günther Maier; Axel Bothur; Jürgen Eckwert; Hans Peter Reisenauer


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
116 KB
Volume
4
Category
Article
ISSN
0947-6539

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## Abstract The reaction between silicon atoms and dimethyl ether (**6**) has been studied in an argon matrix at 10 K and in solid dimethyl ether (**6**) at temperatures up to 80 K. In the initial step, a triplet n‐adduct **T‐5** is formed between a silicon atom and **6**. The next step needs photo