𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Complex of Silylene with Nitrogen: A Combined Matrix-Spectroscopic and Density Functional Theory Study

✍ Scribed by Günther Maier; Hans Peter Reisenauer; Jörg Glatthaar; Roland Zetzmann

Book ID
112005138
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
150 KB
Volume
1
Category
Article
ISSN
1861-4728

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Dimethoxydimethylsilane from Silicon Ato
Dimethoxydimethylsilane from Silicon Atoms and Dimethyl Ether: A Combined Matrix-Spectroscopic and Density Functional Theory Study
✍ Günther Maier; Jörg Glatthaar 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 250 KB

## Abstract The reaction between silicon atoms and dimethyl ether (**6**) has been studied in an argon matrix at 10 K and in solid dimethyl ether (**6**) at temperatures up to 80 K. In the initial step, a triplet n‐adduct **T‐5** is formed between a silicon atom and **6**. The next step needs photo

Catalyzing Aldehyde Hydrosilylation with
Catalyzing Aldehyde Hydrosilylation with a Molybdenum(VI) Complex: A Density Functional Theory Study
✍ Paulo Jorge Costa; Carlos C. Romão; Ana C. Fernandes; Beatriz Royo; Patrícia M. 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 302 KB

## Abstract [MoCl~2~O~2~] catalyzes the hydrosilylation reaction of aldehydes and ketones, as well as the reduction of other related groups, in apparent contrast to its known behavior as an oxidation catalyst. In this work, the mechanism of this reaction is studied by means of density functional th