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Reactions of SiCl 2 and SiHCl with H and Cl Atoms

✍ Scribed by Walch, Stephen P.; Dateo, Christopher E.

Book ID: 120630330
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 92 KB
Volume: 106
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp0126154

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## Abstract The reaction Cl + H~2~CO → HCl + HCO has been studied at 295 K. Chlorine atoms were produced via the infrared laser induced dissociation of CCl~3~F, using a pulsed CO~2~ TEA laser. Using HCl infrared chemiluminescence as the diagnostic, we find the rate constant to be 7.4 ± 0.7 × 10^−11