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Reactions of radical-anions and ethyllithium with silica

✍ Scribed by Jan Kratochvíla; Zdeněk Salajka; Antonín Kazda; Zbyněk Kadlc; Mihnea Gheorghiu


Book ID
113180122
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
266 KB
Volume
121
Category
Article
ISSN
0021-9517

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Reactions of diethylmagnesium - ethyllit
✍ Herman G. Richey Jr.; Julius Farkas Jr. 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 202 KB

In contrast to the reactions of pyridine with diethylmagnesium or ethyllithium alone, which lead only to 1,2-addition, reactions with diethylmagnesium-ethyllithium solutions lead to significant amounts of 1,4-addition; magnesium ate species are proposed to be responsible.