Chemiluminescent Electron-Transfer Reactions of Radical Anions
โ Scribed by Chandross, Edwin A.; Sonntag, Friedrich I.
- Book ID
- 124081739
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 995 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Irradiating cyclohexenones containing an olefinic side chain under electron transferconditions (PET) leads to new spirocyclic products 3, as well as [2+2]-cycloaddition products 2. A new reductive cyclobutane ring opening allows photochemical conversion of cyclobutanes 2 to spirocyclic compounds 3.
Cyclopropyl radicals normally undergo complete thermodynamic equilibration of configuration before they react, e.g., with bromine in the Hunsdiecker reaction'. Incomplete equilibration is normally due to steric or cage effectsa, and to surface effects when cyclopropyl halides are reduced with metals