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Radical anion reactions of cyclobutane derivatives; electron-transfer cleavage of dithymoquinone

โœ Scribed by Robbins, Rebecca J.; Falvey, Daniel E.

Book ID
126814898
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
304 KB
Volume
58
Category
Article
ISSN
0022-3263

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Density functional investigation on elec
Density functional investigation on electron-transfer catalysis of cycloreversion of cyclobutane: Radical anion mechanism
โœ Zheng-Wang Qu; Hui Zhu; Xing-Kang Zhang; Qi-Yuan Zhang ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 107 KB

## Abstract The mechanism of cycloreversion of cyclobutane radical anion (__c__โ€C~4~H) has been investigated at the UB3LYP/6โ€31++G(d,p) level, and compared with those of neutral __c__โ€C~4~H~8~ and __c__โ€C~4~H radical cation. Although both __c__โ€C~4~H and C~2~H~4~ are shown to be Rydberg states unst