Electron transfer. 61. Reactions of the nitrosodisulfonate anion radical with inorganic reductants
โ Scribed by Balasubramanian, P. N.; Gould, E. S.
- Book ID
- 126968734
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 409 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
Cyclopropyl radicals normally undergo complete thermodynamic equilibration of configuration before they react, e.g., with bromine in the Hunsdiecker reaction'. Incomplete equilibration is normally due to steric or cage effectsa, and to surface effects when cyclopropyl halides are reduced with metals
Rate constants have been measured by pulse radiolysis for the reactions of the carbonate radical, COa'-, with a number of organic and inorganic reactants as a function of temperature, generally over the range 5 to 80ยฐC. The reactants include the substitution-inert cyano complexes of Fe", Mo", and W"