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Electron-Transfer Reaction of Radical Anions with Cholesteryl and Cyclocholestanyl Chlorides

✍ Scribed by Cristol, Stanley J.; Barbour, Richard V.

Book ID
126245001
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
270 KB
Volume
88
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Configurational stability of cyclopropyl
Configurational stability of cyclopropyl radicals in electron-transfer reactions with naphthalene radical anion
✍ Gernot Boche; Dieter R. Schneider πŸ“‚ Article πŸ“… 1978 πŸ› Elsevier Science 🌐 French βš– 203 KB

Cyclopropyl radicals normally undergo complete thermodynamic equilibration of configuration before they react, e.g., with bromine in the Hunsdiecker reaction'. Incomplete equilibration is normally due to steric or cage effectsa, and to surface effects when cyclopropyl halides are reduced with metals