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Reactions of propargylamines with derivatives of group VII and VIII metal carbonyls

✍ Scribed by N. E. Kolobova; V. V. Derunov; T. A. Isaeva; V. N. Khandozhko

Book ID
112447152
Publisher
Springer
Year
1988
Tongue
English
Weight
383 KB
Volume
37
Category
Article
ISSN
1573-9171

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I,I,2,2-Tetramethyldisilane reacts with Fez(CO)9 to yield bis(u-dimethylsilylene)-u-car-bony1 bis(tricar-bonylironJ(Fe-Fe). Reaction with octacarbonyldicobalt analogously gives bis(u-dimethylsilylene)bis-(tricarbonylcobalt)(Co-Co) as stable product; spectroscopic results also indicate inter alia the